Bleaches/zat pemutih adalah salah satu komponen penting dalam deterjen.

Kali ini, andy akan menjelaskan tentang mekanisme senyawa pemutih pakaian memutihkan pakaian. Bagaimana cara senyawa itu bisa memutihkan pakaian?

Bleach adalah suatu senyawa yang dapat memutihkan pakaian melalui dua proses, dimana proses pertama adalah meningkatkan efektifitas kerja surfaktan dengan memperkecil ukuran molekul kotoran dengan mengoksidasinya. Sedangkan proses kedua adalah mengubah warna kotoran menjadi putih sehingga tidak tampak /terlihat oleh mata. Warna putih yang dimaksud adalah putih udara, jernih air, bukan putih susu.

saya ulang ya:

Kerja pemutih ini adalah reaksi kimia dimana molekul kotoran akan di pecah – pecah menjadi  bagian yang lebih kecil sehingga lebih mudah untuk di angkat oleh surfaktan (tetap peran surfaktan adalah yang mengangkat noda). Selain itu, secara bersamaan juga  membuat kotoran atau noda menjadi invisible(ora ketok nang mripat bong!!!).

Ini proses pemutih memperkecil molekul kotoran (anonim, 2010):

image

gambar 1. kondisi kotoran yang ada dalam kain. Melekat dalam kain dalam bentuk bulatan, karena merupakan molekul hidrofobik (tidak suka air)

 image

gambar 2. Pemutih akan bereaksi dengan kotoran dimana hasil reaksi ini akan memutuskan ikatan kimia pada kotoran.

image

gambar 3. Akibatnya kotoran menjadi kecil – kecil terpisah pisah.

Ada pertanyaan

kok kotoran yang kecil – kecil itu g kembali bergabung dengan teman – temannya menjadi molekul besar lagi? kan kotoran itu hidrofobik(takut air), maka kotoran akan berkumpul dengan molekul hidrofobik yakni kotoran tetangganya lagi to?. Bayangkan apabila ada minyak tanah dalam air, meskipun kita aduk kuat – kuat, maka apabila jaraknya masih memungkinkan sesama bulatan minyak tanah akan bergabung lagi menjadi bulatan besar?iya to???hayo piye jawabnya??

Nah…jawabannya ini, temen – temen harus juga ingat klo di dalam sistem tersebut juga ada surfaktan yang langsung menyelubungi kotoran kecil – kecil. Surfaktan ini mempunyai dua kemampuan berkebalikan, yakni kemampuan mengikat kotoran tetapi juga mengikat air (sifat liphofilik -hidrofilik=ada bagian dari senyawa yang suka dengan air dan ada yang benci dengan air tapi suka dengan senyawa lipid, seperti kotoran)

 

Oke …lanjut,

gambar dibawah ini, yang sebelah kiri merupakan proses bagaimana pemutih membuat kotoran tidak nampak di mata atau invisible (Anonim, 2010) sedangkan sebelah kanan merupakan penjelasantentang proses bagaimana kotoran tidak nampak di mata  melalui ilmu kimia organik yakni mekanisme reaksi ( andy, 2010):

image   image

 

gambar 1. Semua Senyawa yang berwarna (kecuali ikatan kompleks) memiliki gugus kromophor atau ikatan rangkap terkonjugasi. Begitu pula kotoran, ternyata memiliki ikatanrangkap terkonjugasi (yang dibulat hijau). Molekul pemutih (kita misalkan HX) merupakan senyawa nukleofil atau senyawa yang kaya elektron. Bisa di bayangkan senyawa ini adalah orang kaya yang dermawan, dimana sering sekali memberikan bantuan kepada orang yang membutuhkan. senyawa nukleofil ini akan menyerang kotoran tepat dibagian ikatan rangkap dimana merupakan titik yang miskin elektron atau sering disebut elektrofil.  Anggap elektrofil merupakan orang yang miskin dimana apabila diberi elektron oleh orang kaya akan berubah menjadi stabil)

 

mekanisme yang lebih rinci adalah sebagai berikut:

image

gambar 2. Pada saat kotoran beresonansi (istilah perpindahan ikatan rangkap dalam kimia organik), maka ujung rantai ikatan rangkap akan bermuatan positif sehingga bersifat sangat kekurangan elektron(elektrofil). Pada saat inilah molekul pemutih akan menyerang kotoran.

image  image

image image

Senyawa pemutih akan merusak semua ikatan rangkap yang dimiliki oleh kotoran, sampai tidak memiliki ikatan rangkap terkonjugasi.

dengan terputusnya ikatan ini maka senyawa kotoran menjadi dalam bentuk linier (tidak berikatan rangkap) warna yang terbentuk akibat pola terkonjugasi pun berubah menjadi warna putih bening (maksudnya putih seperti air, seperti udara), bukan putih kain mori yang bercahaya (Jika dalam detergen bisa menyebabkan seperti bercahaya,itu disebabkan oleh suatu senyawa yang disebut optical brightness). Disini lah ada penjelasan mengenai mengapa pemutih yang kuat akan melunturkan warna pakaian menjadi putih kain mori, yakni karena ikatan yang terkonjugasi pada warna pakaian juga akan ikut dirusak oleh senyawa pemutih. namun tenang saja , pada deterjen yang kami formulasikan, kami sudah meninggalkan sistem pemutihan menggunakan senyawa pemutih yang kuat ini, karena selain tidak selektif terhadap kotoran, punya banyak kerugian seperti tidak ramah lingkungan, korosif (tidak cocok untuk mesin cuci). Meskipun demikian, senyawa yang kami formulasikan dalam deterjen, jika hanya senyawa pemutih sendiri memang korosif, namun kami menambahkan senyawa silika yang dapat menghilangkan sifat korosifitas dari senyawa pemutih. Adapun pembahasannya, akan saya ungkap di lain waktu.

 

 

Daftar Pustaka

Andy, 2010. Program chemdraw. dan ilmu kimia organik.

Anonim, 2010, Bleach system, Why use bleach in cleaning products?, science in the box, diakses di alamat http://www.scienceinthebox.com/en_UK/glossary/bleaches_en.html pada tanggal 12 Desember 2010

 

salam

Andy Eko Wibowo

Kepala Laboratorium PT.Indah Semesta Raya

Detergen OXydafit pertama di Indonesia, bersih , ekonomis,& ramah lingkungan

Cocok untuk mesin cuci dan bisnis loundry anda

Telah memiliki surat BPOM dan DEPKES

Selogan saya,

Ilmiahkan semuanya agar anda tak tertipu.

Harga,

ditentukan oleh kantong anda, bisa dengan merk anda.

Pemesanan seluruh Indonesia di layani

4,533 Comments on Mekanisme Senyawa Pemutih Pakaian Memutihkan Pakaian.

  1. It’s understandable that cash can make people independent. But how to act when someone has no cash? The only one way is to get the credit loans or just student loan.

  2. buy essay says:

    You know the structure is really very complicated!
    buy essay

  3. indra says:

    om… tau ga cara ngilangin bintik jamur dibaju?

  4. clara says:

    makasiii
    berguna banget 🙂

  5. lukman says:

    makasih tugas q akhirnya selesai

  6. dwayri says:

    ada gak bahan kimia yang bisa merubah total warna kain/pakaian… kalau ada bahan apa tu… tlng email ya kalau ada…
    terima kasih sebelumnya…

  7. nice post,thanks for sharing! BTW,check out my new android 4.0 tablet China Electronics.

  8. passing says:

    Thank you very much this article well written, learned a lot, and later continue to monitor, there are some recommended XG 910

  9. arief says:

    mohon infonya apakah memungkinkan kain yang berwarna dijadikan putih kembali, misalkan dengan menghilangkan tinta pewarnanya.
    terima kasih

  10. Asep AJ says:

    trims info nya
    izin share ya….

  11. egi says:

    mohon infonya apakah ada yang bisa merubah kain warna menjadi putih atau minimal menjadi pudar menjadi putih

  12. John Pernama K says:

    where i can get the product Oxydafit Detergen ???

  13. Hola! I’ve been reading your blog for a while now and finally
    got the courage too go ahead and give you a shout out from Dallas Texas!
    Just wanted tto tell you keep up the great job!

  14. Beatriz says:

    Hi there, I do think your blog could possibly be having web browser
    compatibility issues. Whenever I look at your
    blog in Safari, it looks fine however when opening in I.E., it has some overlapping issues.
    I simply wanted to give you a quick heads
    up! Apart from that, great website!

  15. Greetings! Verry useful advice in this particular article!
    It is the little changes that make the greatest changes. Thanks
    a lot for sharing!

  16. Howdy, I believe your website may be having internet brrowser comoatibility problems.
    When I look at your blog inn Safari, it looks ffine however,
    if opening in IE, it has some overlapping issues.I
    merely wanted to give you a quick heads up! Apart from that, great site!

  17. Hi, I read your neew stuff daily. Your story-telling style is awesome, keep itt up!

  18. Does your blog have a contact page? I’m having a tough time locdating it but, I’d like to shoot you an email.
    I’ve got some recommendations foor your blog you might be interezted in hearing.
    Either way, great site and I look forward to seeiing it improve over time.

  19. With havin so much written content do you ever run into any issues of plagorism or copyright violation?
    My blog has a lot of completely unique content I’ve either authored myself or outsourced but it appears a lot of it is popping it up all over the web without my permission. Do you know any solutions to help protect against content from being stolen? I’d really appreciate it.

  20. excellent issues altogether, you just received a braand new
    reader. What might you rechommend about your
    ublish that you made a few day ago? Anyy positive?

  21. Hortense says:

    Hi there colleagues, how is all, and what you would like to say on the topic of
    this article, in my view its truly amazing for me.

  22. Heya excellent website! Does running a blog similar
    to thios require a massive amount work? I have virtually no understanding of coding but I haad
    been hoping to start my own blog soon. Anyways, should you have any recommendations
    or tips foor new blog owneers please share.
    I know this is off topic but I just had to ask. Cheers!

  23. {
    {I have|I’ve} been {surfing|browsing} online more than {three|3|2|4} hours today, yet I never found any
    interesting article like yours. {It’s|It is} pretty worth enough for
    me. {In my opinion|Personally|In my view}, if all {webmasters|site owners|website owners|web
    owners} and bloggers made good content as you did, the {internet|net|web} will be {much more|a
    lot more} useful than ever before.|
    I {couldn’t|could not} {resist|refrain from} commenting.

    {Very well|Perfectly|Well|Exceptionally well} written!|
    {I will|I’ll} {right away|immediately} {take hold of|grab|clutch|grasp|seize|snatch} your {rss|rss feed} as I {can not|can’t} {in finding|find|to find} your {email|e-mail} subscription {link|hyperlink} or {newsletter|e-newsletter} service.

    Do {you have|you’ve} any? {Please|Kindly} {allow|permit|let} me
    {realize|recognize|understand|recognise|know} {so
    that|in order that} I {may just|may|could}
    subscribe. Thanks.|
    {It is|It’s} {appropriate|perfect|the best} time to make some plans for the
    future and {it is|it’s} time to be happy. {I have|I’ve} read this post and if I could I {want to|wish to|desire to} suggest you {few|some} interesting things or {advice|suggestions|tips}.
    {Perhaps|Maybe} you {could|can} write next articles referring to this article.
    I {want to|wish to|desire to} read {more|even more} things about
    it!|
    {It is|It’s} {appropriate|perfect|the best} time to make {a few|some} plans for {the future|the longer term|the long run}
    and {it is|it’s} time to be happy. {I have|I’ve} {read|learn} this {post|submit|publish|put up} and
    if I {may just|may|could} I {want to|wish to|desire to} {suggest|recommend|counsel} you {few|some} {interesting|fascinating|attention-grabbing} {things|issues} or {advice|suggestions|tips}.

    {Perhaps|Maybe} you {could|can} write {next|subsequent} articles {relating to|referring
    to|regarding} this article. I {want to|wish to|desire to} {read|learn} {more|even more} {things|issues} {approximately|about} it!|
    {I have|I’ve} been {surfing|browsing} {online|on-line} {more
    than|greater than} {three|3} hours {these days|nowadays|today|lately|as of late}, {yet|but} I {never|by
    no means} {found|discovered} any {interesting|fascinating|attention-grabbing} article like yours.
    {It’s|It is} {lovely|pretty|beautiful} {worth|value|price} {enough|sufficient} for me.
    {In my opinion|Personally|In my view}, if all {webmasters|site owners|website owners|web owners} and bloggers made {just right|good|excellent} {content|content material} as {you did|you probably did}, the {internet|net|web} {will be|shall be|might be|will
    probably be|can be|will likely be} {much more|a lot more} {useful|helpful} than ever
    before.|
    Ahaa, its {nice|pleasant|good|fastidious} {discussion|conversation|dialogue} {regarding|concerning|about|on the
    topic of} this {article|post|piece of writing|paragraph} {here|at this
    place} at this {blog|weblog|webpage|website|web site}, I have read all that, so
    {now|at this time} me also commenting {here|at this place}.|
    I am sure this {article|post|piece of writing|paragraph} has touched all
    the internet {users|people|viewers|visitors}, its really really {nice|pleasant|good|fastidious} {article|post|piece of writing|paragraph} on building up new {blog|weblog|webpage|website|web site}.|
    Wow, this {article|post|piece of writing|paragraph} is
    {nice|pleasant|good|fastidious}, my {sister|younger sister} is
    analyzing {such|these|these kinds of} things, {so|thus|therefore} I am going to {tell|inform|let know|convey} her.|
    {Saved as a favorite|bookmarked!!}, {I really like|I like|I love} {your blog|your site|your web site|your website}!|
    Way cool! Some {very|extremely} valid points! I appreciate you {writing this|penning this} {article|post|write-up} {and the|and also the|plus
    the} rest of the {site is|website is} {also very|extremely|very|also
    really|really} good.|
    Hi, {I do believe|I do think} {this is an excellent|this is a great} {blog|website|web site|site}.
    I stumbledupon it 😉 {I will|I am going to|I’m going to|I may}
    {come back|return|revisit} {once again|yet again} {since I|since i
    have} {bookmarked|book marked|book-marked|saved as a favorite}
    it. Money and freedom {is the best|is the greatest} way to change, may you
    be rich and continue to {help|guide} {other people|others}.|
    Woah! I’m really {loving|enjoying|digging} the template/theme of this {site|website|blog}.

    It’s simple, yet effective. A lot of times it’s {very hard|very difficult|challenging|tough|difficult|hard} to get that “perfect balance”
    between {superb usability|user friendliness|usability} and
    {visual appearance|visual appeal|appearance}. I must say {that you’ve|you
    have|you’ve} done a {awesome|amazing|very good|superb|fantastic|excellent|great} job with this.
    {In addition|Additionally|Also}, the blog loads {very|extremely|super} {fast|quick} for me on {Safari|Internet explorer|Chrome|Opera|Firefox}.
    {Superb|Exceptional|Outstanding|Excellent} Blog!|
    These are {really|actually|in fact|truly|genuinely} {great|enormous|impressive|wonderful|fantastic} ideas
    in {regarding|concerning|about|on the topic of} blogging. You have touched some {nice|pleasant|good|fastidious} {points|factors|things} here.
    Any way keep up wrinting.|
    {I love|I really like|I enjoy|I like|Everyone loves} what you guys {are|are usually|tend to
    be} up too. {This sort of|This type of|Such|This kind of} clever work and {exposure|coverage|reporting}!
    Keep up the {superb|terrific|very good|great|good|awesome|fantastic|excellent|amazing|wonderful} works guys I’ve {incorporated||added|included} you guys to {|my|our||my personal|my own}
    blogroll.|
    {Howdy|Hi there|Hey there|Hi|Hello|Hey}! Someone in my {Myspace|Facebook} group shared this {site|website} with us so I came to
    {give it a look|look it over|take a look|check it out}.
    I’m definitely {enjoying|loving} the information. I’m {book-marking|bookmarking} and will be tweeting
    this to my followers! {Terrific|Wonderful|Great|Fantastic|Outstanding|Exceptional|Superb|Excellent} blog and {wonderful|terrific|brilliant|amazing|great|excellent|fantastic|outstanding|superb} {style and design|design and style|design}.|
    {I love|I really like|I enjoy|I like|Everyone loves} what you guys {are|are usually|tend to be} up too.
    {This sort of|This type of|Such|This kind of} clever work and {exposure|coverage|reporting}!
    Keep up the {superb|terrific|very good|great|good|awesome|fantastic|excellent|amazing|wonderful} works guys I’ve {incorporated|added|included} you guys to {|my|our|my personal|my
    own} blogroll.|
    {Howdy|Hi there|Hey there|Hi|Hello|Hey} would you mind {stating|sharing} which blog platform you’re {working with|using}?
    I’m {looking|planning|going} to start my own blog {in the near future|soon} but I’m
    having a {tough|difficult|hard} time {making a decision|selecting|choosing|deciding} between BlogEngine/Wordpress/B2evolution and Drupal.

    The reason I ask is because your {design and style|design|layout} seems
    different then most blogs and I’m looking for something {completely unique|unique}.
    P.S {My apologies|Apologies|Sorry} for {getting|being} off-topic but I had to ask!|
    {Howdy|Hi there|Hi|Hey there|Hello|Hey} would you mind letting me know which {webhost|hosting company|web host} you’re {utilizing|working with|using}?
    I’ve loaded your blog in 3 {completely different|different} {internet browsers|web browsers|browsers} and I
    must say this blog loads a lot {quicker|faster} then most.
    Can you {suggest|recommend} a good {internet hosting|web hosting|hosting} provider at a {honest|reasonable|fair} price?
    {Thanks a lot|Kudos|Cheers|Thank you|Many thanks|Thanks},
    I appreciate it!|
    {I love|I really like|I like|Everyone loves} it
    {when people|when individuals|when folks|whenever people} {come together|get
    together} and share {opinions|thoughts|views|ideas}.
    Great {blog|website|site}, {keep it up|continue the good work|stick with it}!|
    Thank you for the {auspicious|good} writeup. It in fact was a
    amusement account it. Look advanced to {far|more}
    added agreeable from you! {By the way|However}, how {can|could} we communicate?|
    {Howdy|Hi there|Hey there|Hello|Hey} just wanted to give you a
    quick heads up. The {text|words} in your {content|post|article} seem to be running
    off the screen in {Ie|Internet explorer|Chrome|Firefox|Safari|Opera}.

    I’m not sure if this is a {format|formatting} issue or something to do
    with {web browser|internet browser|browser} compatibility but I {thought|figured} I’d post
    to let you know. The {style and design|design and style|layout|design} look great though!
    Hope you get the {problem|issue} {solved|resolved|fixed} soon. {Kudos|Cheers|Many thanks|Thanks}|
    This is a topic {that is|that’s|which is} {close to|near to}
    my heart… {Cheers|Many thanks|Best wishes|Take care|Thank you}!
    {Where|Exactly where} are your contact details though?|
    It’s very {easy|simple|trouble-free|straightforward|effortless}
    to find out any {topic|matter} on {net|web} as compared to {books|textbooks}, as I found
    this {article|post|piece of writing|paragraph} at this {website|web site|site|web page}.|
    Does your {site|website|blog} have a contact page? I’m having {a tough time|problems|trouble} locating it but, I’d like to {send|shoot} you an {e-mail|email}.
    I’ve got some {creative ideas|recommendations|suggestions|ideas} for your blog you might be interested in hearing.
    Either way, great {site|website|blog} and I look forward to seeing it {develop|improve|expand|grow} over
    time.|
    {Hola|Hey there|Hi|Hello|Greetings}! I’ve been {following|reading} your {site|web site|website|weblog|blog} for {a long
    time|a while|some time} now and finally got the {bravery|courage} to go ahead and give you
    a shout out from {New Caney|Kingwood|Huffman|Porter|Houston|Dallas|Austin|Lubbock|Humble|Atascocita} {Tx|Texas}!
    Just wanted to {tell you|mention|say} keep up the {fantastic|excellent|great|good} {job|work}!|
    Greetings from {Idaho|Carolina|Ohio|Colorado|Florida|Los angeles|California}!
    I’m {bored to tears|bored to death|bored} at work so I decided to {check out|browse} your {site|website|blog} on my iphone during
    lunch break. I {enjoy|really like|love} the {knowledge|info|information} you {present|provide} here and
    can’t wait to take a look when I get home. I’m {shocked|amazed|surprised} at how
    {quick|fast} your blog loaded on my {mobile|cell phone|phone} ..
    I’m not even using WIFI, just 3G .. {Anyhow|Anyways}, {awesome|amazing|very good|superb|good|wonderful|fantastic|excellent|great} {site|blog}!|
    Its {like you|such as you} {read|learn} my {mind|thoughts}!
    You {seem|appear} {to understand|to know|to grasp} {so
    much|a lot} {approximately|about} this, {like you|such as you} wrote the
    {book|e-book|guide|ebook|e book} in it or something. {I think|I feel|I believe} {that you|that you simply|that you just} {could|can} do with {some|a few} {%|p.c.|percent} to {force|pressure|drive|power} the message {house|home} {a bit|a
    little bit}, {however|but} {other than|instead of} that, {this is|that is} {great|wonderful|fantastic|magnificent|excellent} blog.
    {A great|An excellent|A fantastic} read. {I’ll|I will} {definitely|certainly}
    be back.|
    I visited {multiple|many|several|various} {websites|sites|web sites|web pages|blogs} {but|except|however} the audio {quality|feature}
    for audio songs {current|present|existing} at this {website|web site|site|web page} is {really|actually|in fact|truly|genuinely}
    {marvelous|wonderful|excellent|fabulous|superb}.|
    {Howdy|Hi there|Hi|Hello}, i read your blog {occasionally|from time to time} and i own a similar one and i
    was just {wondering|curious} if you get a lot of spam {comments|responses|feedback|remarks}?
    If so how do you {prevent|reduce|stop|protect against} it, any plugin or anything you can {advise|suggest|recommend}?

    I get so much lately it’s driving me {mad|insane|crazy} so
    any {assistance|help|support} is very much appreciated.|
    Greetings! {Very helpful|Very useful} advice {within this|in this particular} {article|post}!
    {It is the|It’s the} little changes {that make|which will make|that produce|that will make} {the biggest|the
    largest|the greatest|the most important|the most significant} changes.
    {Thanks a lot|Thanks|Many thanks} for sharing!|
    {I really|I truly|I seriously|I absolutely} love {your blog|your site|your website}..
    {Very nice|Excellent|Pleasant|Great} colors & theme.
    Did you {create|develop|make|build} {this website|this site|this web site|this amazing site} yourself?
    Please reply back as I’m {looking to|trying to|planning to|wanting to|hoping to|attempting to}
    create {my own|my very own|my own personal} {blog|website|site} and {would like to|want to|would love
    to} {know|learn|find out} where you got this from or {what
    the|exactly what the|just what the} theme {is called|is named}.
    {Thanks|Many thanks|Thank you|Cheers|Appreciate it|Kudos}!|
    {Hi there|Hello there|Howdy}! This {post|article|blog post} {couldn’t|could not}
    be written {any better|much better}! {Reading through|Looking at|Going
    through|Looking through} this {post|article} reminds me of my previous roommate!
    He {always|constantly|continually} kept {talking about|preaching about} this.
    {I will|I’ll|I am going to|I most certainly will} {forward|send} {this article|this information|this post} to him.
    {Pretty sure|Fairly certain} {he will|he’ll|he’s going
    to} {have a good|have a very good|have a great} read. {Thank you for|Thanks for|Many thanks
    for|I appreciate you for} sharing!|
    {Wow|Whoa|Incredible|Amazing}! This blog looks {exactly|just} like my old
    one! It’s on a {completely|entirely|totally}
    different {topic|subject} but it has pretty much the same {layout|page
    layout} and design. {Excellent|Wonderful|Great|Outstanding|Superb} choice of colors!|
    {There is|There’s} {definately|certainly} {a lot to|a great deal to} {know about|learn about|find out about} this {subject|topic|issue}.
    {I like|I love|I really like} {all the|all of the} points {you made|you’ve
    made|you have made}.|
    {You made|You’ve made|You have made} some {decent|good|really good} points there.
    I {looked|checked} {on the internet|on the web|on the net} {for more info|for more information|to find out more|to
    learn more|for additional information} about the issue and found {most individuals|most people} will go along
    with your views on {this website|this site|this web site}.|
    {Hi|Hello|Hi there|What’s up}, I {log on to|check|read} your {new stuff|blogs|blog} {regularly|like every week|daily|on a regular
    basis}. Your {story-telling|writing|humoristic} style is {awesome|witty}, keep {doing what you’re doing|up
    the good work|it up}!|
    I {simply|just} {could not|couldn’t} {leave|depart|go away} your {site|web site|website} {prior to|before} suggesting that I {really|extremely|actually} {enjoyed|loved} {the standard|the usual} {information|info} {a person|an individual} {supply|provide} {for your|on your|in your|to your} {visitors|guests}?
    Is {going to|gonna} be {back|again} {frequently|regularly|incessantly|steadily|ceaselessly|often|continuously}
    {in order to|to} {check up on|check out|inspect|investigate cross-check}
    new posts|
    {I wanted|I needed|I want to|I need to} to thank you for this {great|excellent|fantastic|wonderful|good|very good} read!!
    I {definitely|certainly|absolutely} {enjoyed|loved} every {little bit of|bit of} it.
    {I have|I’ve got|I have got} you {bookmarked|book marked|book-marked|saved
    as a favorite} {to check out|to look at} new {stuff you|things you} post…|
    {Hi|Hello|Hi there|What’s up}, just wanted to {mention|say|tell you}, I {enjoyed|liked|loved} this {article|post|blog post}.
    It was {inspiring|funny|practical|helpful}.
    Keep on posting!|
    {Hi there|Hello}, I enjoy reading {all of|through} your {article|post|article post}.
    I {like|wanted} to write a little comment to support you.|
    I {always|constantly|every time} spent my half an hour to read this {blog|weblog|webpage|website|web site}’s {articles|posts|articles or reviews|content} {everyday|daily|every day|all
    the time} along with a {cup|mug} of coffee.|
    I {always|for all time|all the time|constantly|every time} emailed this {blog|weblog|webpage|website|web site} post page to all
    my {friends|associates|contacts}, {because|since|as|for the reason that} if like to read it {then|after that|next|afterward} my {friends|links|contacts} will too.|
    My {coder|programmer|developer} is trying to {persuade|convince} me to move to .net from PHP.
    I have always disliked the idea because of the {expenses|costs}.
    But he’s tryiong none the less. I’ve been using {Movable-type|WordPress} on {a number of|a variety of|numerous|several|various}
    websites for about a year and am {nervous|anxious|worried|concerned} about switching to another platform.

    I have heard {fantastic|very good|excellent|great|good} things
    about blogengine.net. Is there a way I can {transfer|import} all my wordpress {content|posts}
    into it? {Any kind of|Any} help would be {really|greatly} appreciated!|
    {Hello|Hi|Hello there|Hi there|Howdy|Good day}! I could have sworn I’ve {been to|visited} {this blog|this web site|this website|this site|your blog} before but after {browsing through|going through|looking at}
    {some of the|a few of the|many of the} {posts|articles} I realized it’s new to me.
    {Anyways|Anyhow|Nonetheless|Regardless}, I’m {definitely|certainly} {happy|pleased|delighted} {I
    found|I discovered|I came across|I stumbled upon} it
    and I’ll be {bookmarking|book-marking} it and checking back {frequently|regularly|often}!|
    {Terrific|Great|Wonderful} {article|work}! {This is|That is} {the type of|the kind of}
    {information|info} {that are meant to|that are supposed to|that should} be
    shared {around the|across the} {web|internet|net}. {Disgrace|Shame} on {the {seek|search} engines|Google}
    for {now not|not|no longer} positioning this {post|submit|publish|put up} {upper|higher}!
    Come on over and {talk over with|discuss with|seek advice
    from|visit|consult with} my {site|web site|website} .
    {Thank you|Thanks} =)|
    Heya {i’m|i am} for the first time here. I {came across|found} this board and I
    find It {truly|really} useful & it helped me out {a lot|much}.

    I hope to give something back and {help|aid} others like you {helped|aided} me.|
    {Hi|Hello|Hi there|Hello there|Howdy|Greetings}, {I think|I believe|I do believe|I
    do think|There’s no doubt that} {your site|your website|your
    web site|your blog} {might be|may be|could be|could possibly be} having {browser|internet browser|web browser} compatibility {issues|problems}.

    {When I|Whenever I} {look at your|take a look at your} {website|web site|site|blog} in Safari, it looks
    fine {but when|however when|however, if|however, when} opening in {Internet Explorer|IE|I.E.}, {it has|it’s got} some overlapping issues.
    {I just|I simply|I merely} wanted to {give you a|provide you with a} quick heads up!
    {Other than that|Apart from that|Besides that|Aside from that}, {fantastic|wonderful|great|excellent} {blog|website|site}!|
    {A person|Someone|Somebody} {necessarily|essentially}
    {lend a hand|help|assist} to make {seriously|critically|significantly|severely} {articles|posts} {I would|I might|I’d} state.

    {This is|That is} the {first|very first} time I frequented
    your {web page|website page} and {to this point|so far|thus far|up to now}?
    I {amazed|surprised} with the {research|analysis} you made to {create|make} {this actual|this particular} {post|submit|publish|put up} {incredible|amazing|extraordinary}.
    {Great|Wonderful|Fantastic|Magnificent|Excellent} {task|process|activity|job}!|
    Heya {i’m|i am} for {the primary|the first} time here.
    I {came across|found} this board and I {in finding|find|to find} It {truly|really} {useful|helpful} & it helped me out
    {a lot|much}. {I am hoping|I hope|I’m hoping} {to give|to offer|to provide|to present} {something|one thing} {back|again} and {help|aid}
    others {like you|such as you} {helped|aided} me.|
    {Hello|Hi|Hello there|Hi there|Howdy|Good day|Hey there}!
    {I just|I simply} {would like to|want to|wish to} {give you a|offer you
    a} {huge|big} thumbs up {for the|for your} {great|excellent} {info|information}
    {you have|you’ve got|you have got} {here|right here} on this post.
    {I will be|I’ll be|I am} {coming back to|returning to} {your blog|your
    site|your website|your web site} for more soon.|
    I {always|all the time|every time} used to {read|study} {article|post|piece of writing|paragraph}
    in news papers but now as I am a user of {internet|web|net} {so|thus|therefore} from now I am
    using net for {articles|posts|articles or reviews|content}, thanks to web.|
    Your {way|method|means|mode} of {describing|explaining|telling} {everything|all|the whole thing} in this {article|post|piece of
    writing|paragraph} is {really|actually|in fact|truly|genuinely} {nice|pleasant|good|fastidious}, {all|every
    one} {can|be able to|be capable of} {easily|without difficulty|effortlessly|simply}
    {understand|know|be aware of} it, Thanks a lot.|
    {Hi|Hello} there, {I found|I discovered} your {blog|website|web site|site} {by means of|via|by
    the use of|by way of} Google {at the same time as|whilst|even as|while} {searching for|looking for} a
    {similar|comparable|related} {topic|matter|subject}, your
    {site|web site|website} {got here|came} up, it {looks|appears|seems|seems to be|appears to be
    like} {good|great}. {I have|I’ve} bookmarked it in my google
    bookmarks.
    {Hello|Hi} there, {simply|just} {turned into|became|was|become|changed into}
    {aware of|alert to} your {blog|weblog} {thru|through|via} Google, {and found|and located}
    that {it is|it’s} {really|truly} informative.
    {I’m|I am} {gonna|going to} {watch out|be careful}
    for brussels. {I will|I’ll} {appreciate|be grateful} {if you|should you|when you|in the event you|in case you|for those who|if you happen to} {continue|proceed} this {in future}.
    {A lot of|Lots of|Many|Numerous} {other folks|folks|other people|people} {will
    be|shall be|might be|will probably be|can be|will likely be} benefited
    {from your|out of your} writing. Cheers!|
    {I am|I’m} curious to find out what blog {system|platform} {you have been|you
    happen to be|you are|you’re} {working with|utilizing|using}?
    I’m {experiencing|having} some {minor|small} security {problems|issues} with my latest {site|website|blog} and {I would|I’d}
    like to find something more {safe|risk-free|safeguarded|secure}.
    Do you have any {solutions|suggestions|recommendations}?|
    {I am|I’m} {extremely|really} impressed with your writing skills {and also|as well as} with
    the layout on your {blog|weblog}. Is this a paid theme or did you {customize|modify} it yourself?

    {Either way|Anyway} keep up the {nice|excellent} quality
    writing, {it’s|it is} rare to see a {nice|great} blog like this one {these
    days|nowadays|today}.|
    {I am|I’m} {extremely|really} {inspired|impressed} {with your|together with your|along with your} writing
    {talents|skills|abilities} {and also|as {smartly|well|neatly} as} with the {layout|format|structure} {for your|on your|in your|to your} {blog|weblog}.
    {Is this|Is that this} a paid {subject|topic|subject matter|theme} or did you {customize|modify} it {yourself|your self}?
    {Either way|Anyway} {stay|keep} up the {nice|excellent} {quality|high quality} writing, {it’s|it is} {rare|uncommon}
    {to peer|to see|to look} a {nice|great} {blog|weblog} like this one {these days|nowadays|today}..|
    {Hi|Hello}, Neat post. {There is|There’s} {a problem|an issue} {with your|together with your|along with your} {site|web site|website}
    in {internet|web} explorer, {may|might|could|would} {check|test} this?
    IE {still|nonetheless} is the {marketplace|market} {leader|chief} and {a large|a good|a big|a huge} {part of|section of|component
    to|portion of|component of|element of} {other
    folks|folks|other people|people} will {leave out|omit|miss|pass over} your {great|wonderful|fantastic|magnificent|excellent} writing {due to|because of}
    this problem.|
    {I’m|I am} not sure where {you are|you’re} getting your {info|information}, but
    {good|great} topic. I needs to spend some time learning {more|much more} or understanding more.

    Thanks for {great|wonderful|fantastic|magnificent|excellent} {information|info} I was looking for this {information|info} for my
    mission.|
    {Hi|Hello}, i think that i saw you visited my {blog|weblog|website|web site|site} {so|thus} i came to “return the
    favor”.{I am|I’m} {trying to|attempting to} find things to {improve|enhance} my {website|site|web site}!I suppose its ok
    to use {some of|a few of} your ideas!!|
    {Hi|Hello}, {i think|i feel|i believe} that i {saw|noticed} you visited my {blog|weblog|website|web site|site} {so|thus} i {got here|came} to
    {go back|return} the {prefer|choose|favor|want|desire}?.{I am|I’m} {trying to|attempting to} {in finding|find|to find}
    {things|issues} to {improve|enhance} my {website|site|web site}!{I guess|I
    assume|I suppose} its {good enough|ok|adequate} {to use|to make
    use of} {some of|a few of} your {ideas|concepts|ideas}!!|
    {Hello|Hi} there, just became {aware of|alert
    to} your blog through Google, and found that {it is|it’s} {really|truly}
    informative. {I’m|I am} {gonna|going to} watch out for
    brussels. {I will|I’ll} {appreciate|be grateful} if you continue this {in future}.
    {A lot of|Lots of|Many|Numerous} people will be benefited from your writing.
    Cheers!|
    {I’m|I am} {now not|not|no longer} {sure|positive|certain}
    {where|the place} {you are|you’re} getting your {info|information}, {however|but} {good|great} topic.
    I {needs to|must} spend {a while|some time} {studying|learning|finding out} {more|much more} or {working out|understanding|figuring out} more.

    {Thank you|Thanks} for {great|wonderful|fantastic|magnificent|excellent} {information|info} {I used to be|I was} {looking for|in search of|on the lookout
    for|searching for} this {information|info} for my mission.|
    {Hi|Hello} my {family member|loved one|friend}!
    I {want to|wish to} say that this {article|post} is {awesome|amazing}, {great|nice} written and {come with|include} {almost|approximately} all {important|significant|vital} infos.
    {I’d|I would} like {to peer|to see|to look} {more|extra} posts like
    this .|
    {hi|hello}!,{I love|I really like|I like} your
    writing {so|very} {so much|much|a lot}! {percentage|proportion|share} we {keep in touch|keep up a
    correspondence|communicate|be in contact} {more|extra} {approximately|about} your {post|article} on AOL?
    I {need|require} {an expert|a specialist} {in this|on this} {space|area|house} {to solve|to
    unravel|to resolve} my problem. {May be|Maybe} {that is|that’s} you!
    {Taking a look|Looking|Having a look} {forward|ahead} {to peer|to see|to look} you.
    |
    {I am|I’m} really {loving|enjoying} the theme/design of your {site|weblog|web site|website|blog}.
    Do you ever run into any {web browser|internet browser|browser} compatibility {problems|issues}?
    A {number of|handful of|couple of|small number of|few of} my blog {audience|visitors|readers} have complained about my {blog|website|site} not {operating|working} correctly in Explorer but looks
    great in {Safari|Chrome|Opera|Firefox}. Do you have any {solutions|ideas|advice|tips|suggestions|recommendations} to help fix this {issue|problem}?|
    {Good|Great|Very good} {info|information}. Lucky me {I found|I
    discovered|I came across|I ran across|I recently found} {your website|your site|your blog} {by accident|by chance} (stumbleupon).

    {I have|I’ve} {bookmarked it|saved it|book marked it|book-marked
    it|saved as a favorite} for later!|
    It’s {great|enormous|impressive|wonderful|fantastic}
    that you are getting {ideas|thoughts} from this {article|post|piece of writing|paragraph} as well as from our {discussion|argument|dialogue} made {here|at this place|at this time}.|
    If you {want|desire|wish for|would like} to {increase|improve|grow} your {experience|knowledge|familiarity|know-how}
    {only|simply|just} keep visiting this {website|web site|site|web page} and
    be updated with the {latest|newest|most recent|most up-to-date|hottest} {news|information|gossip|news
    update} posted here.|
    What’s {Taking place|Happening|Going down} {i’m|i am} new to this,
    I stumbled upon this {I have|I’ve} {found|discovered} It
    {positively|absolutely} {helpful|useful} and it has {helped|aided} me out loads.
    {I am hoping|I hope|I’m hoping} to {give a contribution|contribute} {other|different} {users|customers} like its {helped|aided} me.
    {Good|Great} job.|
    {Wow|Hurrah}, that’s what I was {looking|searching|seeking|exploring} for, what a {stuff|information|data|material}!
    {present|existing} here at this {blog|weblog|webpage|website|web site}, thanks admin of
    this {website|web site|site|web page}.|
    If you {want|desire|wish for|would like} to {take|get|obtain}
    {much|a great deal|a good deal} from this {article|post|piece of writing|paragraph} then you have to apply
    {such|these} {strategies|techniques|methods} to your won {blog|weblog|webpage|website|web site}.|
    It’s an {awesome|remarkable|amazing} {article|post|piece of writing|paragraph} {for|designed for|in favor of|in support of}
    all the {internet|web|online} {users|people|viewers|visitors}; they will {take|get|obtain} {benefit|advantage} from it I am sure.|
    {I’ve|I have} {read|learn} {some|several|a few} {just right|good|excellent} stuff here.
    {Definitely|Certainly} {worth|value|price} bookmarking for revisiting.
    I {wonder|surprise} how {so much|much|a lot} {attempt|effort} {you put|you set|you place} to {create|make}
    {this type of|this kind of|this sort of|such a|one of these|any such|the
    sort of} {great|wonderful|fantastic|magnificent|excellent} informative {site|web site|website}.|
    {This is a|That is a} {very good|great|good|really good} tip {especially|particularly} to those {new to|fresh to} the blogosphere.
    {Brief|Short|Simple} but very {accurate|precise} {information|info}…
    {Thanks for|Thank you for|Many thanks for|Appreciate your} sharing
    this one. A must read {article|post}!|
    {I’ve|I have} been exploring for {a little bit|a little|a
    bit} for any {high-quality|high quality} articles or
    {blog|weblog} posts {in this|on this} {kind of|sort
    of} {space|area|house} . Exploring in Yahoo I {at last|eventually|finally|ultimately} stumbled upon this {site|web site|website}.
    {Reading|Studying} this {info|information} So {i’m|i am} {satisfied|glad|happy} to {express|show|exhibit|convey} that {I have|I’ve} {a very|an incredibly} {just right|good|excellent} uncanny feeling
    I {found out|came upon|discovered} {exactly|just} what I needed.
    I {so much|such a lot|most} {without a doubt|no doubt|undoubtedly|surely|certainly|for sure|definitely|unquestionably|indisputably|indubitably} will make {certain|sure} to
    {don?t|do not} {put out of your mind|forget|fail to remember|overlook|disregard|omit} this {site|web site|website} {and
    give|and provides} it {a look|a glance} {on {a constant|a continuing|a relentless} basis|regularly}.|
    Having read this {I thought it was|I believed it was}
    {very|really|extremely|rather} {informative|enlightening}.
    I appreciate you {taking the time|finding the time|spending some time}
    {and effort|and energy} to put {this article|this short article|this informative article|this information|this content} together.
    I once again find {myself|myself personally} spending {way
    too much|a significant amount of|a lot of} time both reading and {commenting|leaving comments|posting comments}.
    But so what, it was still {worth it|worthwhile}!|
    Quality {articles|posts|articles or reviews|content} is the {key|secret|important|main|crucial} to {attract|be
    a focus for|invite|interest} the {users|people|viewers|visitors} to {visit|go to see|pay a
    visit|pay a quick visit} the {website|web site|site|web page},
    that’s what this {website|web site|site|web paglId151b7deedbb9815215121817331

  24. Una says:

    Hola! I’ve been reading your website for a long time now and finally
    got the bravery to go ahead and give you a shout ouut from Kingwood Tx!
    Just wanted too say keep up the excellent job!

  25. Hassie says:

    What i don’t realize is inn truth how you’re not actually much more neatly-liked than you
    mivht be now. Yoou are very intelligent. You recognize thus considerably when itt comes to this subject, produced me
    individually imagine it from a llot of numerous angles.
    Its like men and women don’t seem to be interested unless
    it is one thimg to do with Woman gaga! Your personal stuffs excellent.
    At all times tae care of it up!

  26. Warren says:

    Wonderful post however I was wondering if you could write
    a litte more on this subject? I’d be very thankful if
    you could elabborate a little bit further. Thank you!

  27. google.net says:

    Job seekers need to fill-in an effective application form
    together with the general aspects and distribute the form with the selected financial institution’s site The
    bank and financial services are some of thee main front side runners which gives the services to manage the money things

  28. Hello, this weekend is pleasant in favor of me, for the
    reason that this moment i am reading this great informative
    paragraph here at my residence.

  29. porn videos says:

    free animal sex pics

  30. I could not resist commenting. Exceptionally well written!

  31. Appreciation to my father who informed me concerning this weblog, this weblog is really awesome.

  32. xxx says:

    Appreciating the hard work you put into your website and
    detailed information you provide. It’s great to come across
    a blog every once in a while that isn’t the same old
    rehashed material. Fantastic read! I’ve bookmarked your
    site and I’m adding your RSS feeds to my Google account.

  33. I am curious to find out what blog platform you happen to be working with?
    I’m having some minor security problems with my latest website
    and I’d like to find something more safeguarded.
    Do you have any solutions?

  34. I will right away grab your rss feed as I can’t to find your e-mail subscription hyperlink or e-newsletter service. Do you have any? Please permit me realize in order that I may just subscribe. Thanks.

  35. hey there and thank you for your information – I have certainly picked
    up something new from right here. I did however expertise a few technical points using this web site, since
    I experienced to reload the site lots of times previous to I could get it to
    load correctly. I had been wondering if your web host is OK?
    Not that I’m complaining, but slow loading instances times will very
    frequently affect your placement in google and can damage your
    high-quality score if advertising and marketing with Adwords.

    Anyway I’m adding this RSS to my email and can look out
    for a lot more of your respective intriguing content.
    Make sure you update this again very soon.

  36. Keep on working, great job!

  37. ควย says:

    Hello! Do you know if they make any plugins to protect against hackers?
    I’m kinda paranoid about losing everything I’ve worked hard on. Any recommendations?

  38. Thanks for your personal marvelous posting!
    I really enjoyed reading it, you might be a great author.I will always bookmark your blog and
    will eventually come back in the foreseeable
    future. I want to encourage one to continue your great posts,
    have a nice morning!

  39. xxxx says:

    Very good article. I am facing some of these issues as well..

  40. Hurrah! Finally I got a web site from where I can genuinely get
    useful data regarding my study and knowledge.

  41. I loved as much as you will receive carried out right here.
    The sketch is attractive, your authored subject matter stylish.
    nonetheless, you command get bought an shakiness over that you wish be delivering the following.
    unwell unquestionably come further formerly again as
    exactly the same nearly very often inside case you shield this increase.

  42. A fascinating discussion is worth comment.
    I believe that you need to write more on this topic, it might not be a taboo
    subject but generally folks don’t speak about such issues.
    To the next! Many thanks!!

  43. Greate post. Keep writing such kind of info on your blog.

    Im really impressed by it.
    Hi there, You have performed a fantastic job. I’ll certainly digg it and
    in my view recommend to my friends. I’m confident they
    will be benefited from this website.

  44. ควย says:

    Hello there, just became alert to your blog through Google, and found that it is
    really informative. I’m going to watch out for brussels. I’ll be
    grateful if you continue this in future. Lots of people will be
    benefited from your writing. Cheers!

  45. xnxx says:

    Your style is unique compared to other folks I have read stuff from.

    Many thanks for posting when you’ve got the opportunity, Guess I will
    just bookmark this web site.

  46. หี says:

    Hello There. I found your blog using msn. This is
    a really well written article. I’ll make sure to bookmark it and return to read more of your useful information. Thanks
    for the post. I will definitely return.

  47. Appreciate the recommendation. Let me try it out.

  48. EdzardNall says:

    viagra buy
    [url=http://viagra-withoutdoctorprescription.net]viagra without a doctor prescription[/url] viagra tablets/capsules
    viagra without a doctor prescription – buy viagra online overnight delivery lee county tree
    viagra dose medications contact info

  49. beeg says:

    Hello to all, since I am actually keen of reading this blog’s post to be updated regularly.
    It includes fastidious material.

Leave a Reply